金属学报  2012, Vol. 48 Issue (9): 1103-1108    DOI: 10.3724/SP.J.1037.2012.00329

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锆合金在LiOH水溶液中腐蚀的各向异性研究

孙国成1, 2), 周邦新1, 2), 姚美意1, 2), 谢世敬1, 2), 李强1, 2)

1) 上海大学微结构重点实验室, 上海 200444 2) 上海大学材料研究所, 上海 200072

STUDY OF ANISOTROPIC BEHAVIOR FOR ZIRCONIUM ALLOYS CORRODED IN LITHIATED WATER

SUN Guocheng1, 2), ZHOU Bangxin1, 2), YAO Meiyi1, 2),  XIE Shijing1, 2),  LI Qiang 1, 2)

1) Laboratory for Microstructures, Shanghai University, Shanghai 200444 2) Institute of Materials, Shanghai University, Shanghai 200072

孙国成 周邦新 姚美意 谢世敬 李强. 锆合金在LiOH水溶液中腐蚀的各向异性研究[J]. 金属学报, 2012, 48(9): 1103-1108.
, , , , . STUDY OF ANISOTROPIC BEHAVIOR FOR ZIRCONIUM ALLOYS CORRODED IN LITHIATED WATER[J]. Acta Metall Sin, 2012, 48(9): 1103-1108.

摘要 参考文献 相关文章 Metrics 全文: PDF(2156 KB)   摘要: 选用了具有相同织构的Zr-4, N18和ZIRLO锆合金片状样品, 利用高压釜在360℃,  18.6 MPa的0.01 mol/L LiOH水溶液中进行了280 d腐蚀实验, 采用EBSD和SEM研究了织构及合金成分对锆合金耐腐蚀性能的影响. 结果表明, 腐蚀280 d后, Zr-4样品表现出明显的腐蚀各向异性特征, 在织构因子较大的轧面(SN面)上氧化膜较厚, 耐腐蚀性能差, 而在织构因子较小的垂直于轧向的截面(SR面)和垂直于横向的截面(ST面)上氧化膜较薄, 耐腐蚀性能好. 添加合金元素Nb的N18和ZIRLO样品氧化膜生长的各向异性受到抑制, 在SN, SR和ST 3个不同面上氧化膜的厚度相同, 耐腐蚀性能比Zr-4样品的SN面优良. 但是, 如果只以样品的SR和ST面进行比较, 氧化膜的生长速率会随Nb含量的增加而增大, 耐腐蚀性能变差. 从改善合金的耐腐蚀性能考虑, Nb的添加量不应该高于0.3%(质量分数). 关键词 ： 锆合金,  织构,  氧化各向异性,  耐腐蚀性能,  Nb     Abstract：Zirconium alloys of a hexagonal close--packed crystal structure have prominent anisotropic characteristic in comparison with metals of a cubic crystal structure and a strong texture is produced in sheet or tubular materials during the fabrication process. The anisotropic characteristic is bound to be reflected on the corrosion behavior of zirconium alloys. In order to investigate the effect of texture and compositions on the anisotropic growth of oxide layer formed on zirconium alloys and clarify the mechanism of improving corrosion resistance by adding Nb in zirconium alloys, Zr-4, N18 and ZIRLO zirconium alloys with different contents of Nb were adopted as the experimental materials. All the plate specimens of zirconium alloys 2 mm in thickness have a similar texture. Corrosion tests were carried out in a static autoclave at 360 ℃, 18.6 MPa in lithiated water with 0.01 mol/L LiOH. The results show that the anisotropic growth of oxide layer on different surfaces of the specimens was only observed for Zr-4 specimen but not for N18 and ZIRLO specimens. The thickness of oxide layer develops much faster on the rolling surface (SN surface) than that on the surface perpendicular to the rolling direction (SR surface) and the surface perpendicular to the transversal direction (ST surface) for Zr-4 specimen after 90-100 d exposure, and the corrosion resistance on the SR and ST surfaces was much better than that on the SN surface. However, for N18 and ZIRLO specimens the anisotropic growth of oxide layer was restrained by the addition of Nb, and the oxide thickness on these three different surfaces was the same after 280 d exposure. Therefore the corrosion resistance of N18 and ZIRLO sheet or tubular specimens was superior to Zr-4 corroded in lithiated water, because the oxide layers grew mainly on the SN surface of the specimens. If making a comparison among Zr-4, N18 and ZIRLO specimens about the growth rate of oxide layers only on the SR and ST surfaces, it is shown that the growth rate of oxide layers increased with the increase of Nb content in these alloys. From a point of view for the improving corrosion resistance, the addition of Nb no more than 0.3\% (mass fraction) is recommended. Key words： zirconium alloy    texture    anisotropic oxidation    corrosion resistance    Nb 收稿日期: 2012-06-06      基金资助: 国家自然科学基金资助项目50971084 作者简介: 孙国成, 男, 1987年生, 硕士生 服务 把本文推荐给朋友 加入引用管理器 E-mail Alert RSS 作者相关文章 孙国成 周邦新 姚美意 谢世敬 李强 44.8K 链接本文: https://www.ams.org.cn/CN/10.3724/SP.J.1037.2012.00329      或      https://www.ams.org.cn/CN/Y2012/V48/I9/1103 [1] Garzarolli F, Seidel H, Tricot R, Gros J P. In: Eucken C M, Garde A M eds., Zirconium in the Nuclear Industry: 9th International Symposium, ASTM STP 1132, Baltimore: ASTM International, 1991: 395 [2] Yilmazbayhan A, Breval E, Motta A T, Comstock R J. J Nucl Mater, 2006; 349: 265 [3] Zhou B X, Li Q, Yao M Y, Liu W Q, Chu Y L. In: Kammenzind B, Limb¨ack M eds., Zirconium in the Nuclear Industry: 15th International Symposium, ASTM STP 1505, Baltimore: ASTM International, 2009: 360 [4] Park J Y, Choi B K, Yoo S J, Jeong Y H. In: Kammenzind B, Limb¨ack M eds., Zirconium in the Nuclear Industry: 15th International Symposium, ASTM STP 1505, Baltimore: ASTM International, 2009: 471 [5] Kim H G, Kim T H, Jeong Y H. J Nucl Mater, 2002; 306: 44 [6] Zhou B X, Peng J C, Yao M Y, Li Q, Xia S, Du C X, Xu G. In: Limb¨ack M, Barb´eris P eds., Zirconium in the Nuclear Industry: 16th International Symposium, ASTM STP 1529, Bridgeport: ASTM International, 2011: 620 [7] Charquet D, Tricot R, Wadier J E. In: Van Swam L F P, Eucken C M eds., Zirconium in the Nuclear Industry: 8th International Symposium, ASTM STP 1023, Baltimore: ASTM International, 1989: 374 [8] Wang C T, Eucken C M, Graham R A. In: Eucken C M,  Garde A M eds., Zirconium in the Nuclear Industry: 9th International Symposium, ASTM STP 1132, Baltimore: ASTM International, 1991: 319 [9] Kearns J J. Report No.WAPD–TM–472, Report of Westinghouse Electric Corporation, Bettis Atomic Power Laboratory, Pittsburgh, PA, 1965: 2 [10] Han J H, Rheem K S. J Nucl Mater, 1994; 217: 197 [11] Pecheur D, Godlewski J, Billot P, Thomazet J. In: Sabol G P, Bradley E R eds., Zirconium in the Nuclear Industry: 11th International Symposium, ASTM STP 1295, Ann Arbor: ASTM International, 1996: 94 [12] Sabol G P, Kilp G R, Balfour M G, Roberts E. In: Van Swam L F P, Eucken C M eds., Zirconium in the Nuclear Industry: 8th International Symposium, ASTM STP 1023, Baltimore: ASTM International, 1989: 227 [13] Nikulina A V, Markelov V A, Peregud M M, Bibilashvili Y K, Kotrekhov V A, Lositsky A F, Kuzmenko N V, Shevnin YP, ShamardinVK, KobylyanskyGP, NovoselovAE. In: Sabol G P, Bradley E R eds., Zirconium in the Nuclear Industry: 11th International Symposium, ASTM STP 1295, Ann Arbor: ASTM International, 1996: 785 [14] Zhou B X, Li Q, Huang Q, Miao Z, Zhao W J, Li C. Nucl Power Eng, 2000; 21: 439 (周邦新, 李强, 黄强, 苗 志, 赵文金, 李聪. 核动力工程, 2000; 21: 439) [15] Zhou B X, Yao M Y, Li Z K,Wang X M, Zhou J, Long C S, Liu Q, Luan B F. J Mater Sci Technol, 2012; 28: 606 [16] Zhou B X, Li Q, YaoMY, LiuWQ, Chu Y L. Nucl Power Eng, 2005; 26: 364 (周邦新, 李强, 黄 强, 苗 志, 赵文金, 李 聪. 核动力工程, 2000; 21: 439) [17] Zhou B X, Li Q, Yao M Y, Liu W Q, Chu Y L. Corros Prot, 2009; 30: 589 (周邦新, 李强, 姚美意, 刘文庆, 褚于良. 腐蚀与防护, 2009; 30: 589) [18] Du C X, Peng J C, Li H, Zhou B X. Acta Metall Sin, 2011; 47: 887 (杜晨曦, 彭剑超, 李慧, 周邦新. 金属学报, 2011; 47: 887) [19] Geng J Q, Zhou B X, Yao M Y, Wang J H, Zhang X, Li S L, Du C X. J Shanghai Univ (Nat Sci Ed), 2011; 17: 293 (耿建桥, 周邦新, 姚美意, 王锦红, 张欣, 李士炉, 杜晨曦. 上海大学学报(自然科学版), 2011; 17: 293) [20] Cox B. J Nucl Mater, 2005; 336: 331 [21] Liu W Q, Zhou B X, Li Q. Nucl Power Eng, 2002; 23: 68 (刘文庆, 周邦新, 李强. 核动力工程, 2002; 23: 68) [22] Zhou B X, Yao M Y, Li Q, Xia S, Liu W Q, Chu Y L. Rare Met Mater Eng, 2007; 36: 1317 (周邦新, 姚美意, 李强, 夏爽, 刘文庆, 褚于良. 稀有金属材料与工程, 2007; 36: 1317) [1] 常松涛, 张芳, 沙玉辉, 左良. 偏析干预下体心立方金属再结晶织构竞争[J]. 金属学报, 2023, 59(8): 1065-1074. [2] 刘兴军, 魏振帮, 卢勇, 韩佳甲, 施荣沛, 王翠萍. 新型钴基与Nb-Si基高温合金扩散动力学研究进展[J]. 金属学报, 2023, 59(8): 969-985. [3] 司永礼, 薛金涛, 王幸福, 梁驹华, 史子木, 韩福生. Cr添加对孪生诱发塑性钢腐蚀行为的影响[J]. 金属学报, 2023, 59(7): 905-914. [4] 冯艾寒, 陈强, 王剑, 王皞, 曲寿江, 陈道伦. 低密度Ti2AlNb基合金热轧板微观组织的热稳定性[J]. 金属学报, 2023, 59(6): 777-786. [5] 廖京京, 张伟, 张君松, 吴军, 杨忠波, 彭倩, 邱绍宇. Zr-Sn-Nb-Fe-V合金在过热蒸汽中的周期性钝化-转折行为[J]. 金属学报, 2023, 59(2): 289-296. [6] 姜江, 郝世杰, 姜大强, 郭方敏, 任洋, 崔立山. NiTi-Nb原位复合材料的准线性超弹性变形[J]. 金属学报, 2023, 59(11): 1419-1427. [7] 娄峰, 刘轲, 刘金学, 董含武, 李淑波, 杜文博. 轧制态Mg-xZn-0.5Er合金板材组织及室温成形性能[J]. 金属学报, 2023, 59(11): 1439-1447. [8] 梁琛, 王小娟, 王海鹏. 快速凝固Ti-Al-Nb合金B2相形成机制与显微力学性能[J]. 金属学报, 2022, 58(9): 1169-1178. 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