金属学报  2011, Vol. 47 Issue (9): 1200-1204    DOI: 10.3724/SP.J.1037.2011.00103

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含Nb锆合金中第二相的吸放氢性能

王锦红, 王荣山, 翁立奎, 张晏玮, 耿建桥

苏州热工研究院有限公司, 苏州 215004

HYDROGEN ABSORPTION AND DESORPTION PERFORMANCES OF THE SECOND PHASES IN ZIRCONIUM ALLOY WITH Nb

WANG Jinhong, WANG Rongshan, WENG Likui, ZHANG Yanwei, GENG Jianqiao

Suzhou Nuclear Power Research Institute, Suzhou 215004

王锦红 王荣山 翁立奎 张晏玮 耿建桥. 含Nb锆合金中第二相的吸放氢性能[J]. 金属学报, 2011, 47(9): 1200-1204.
, , , , . HYDROGEN ABSORPTION AND DESORPTION PERFORMANCES OF THE SECOND PHASES IN ZIRCONIUM ALLOY WITH Nb[J]. Acta Metall Sin, 2011, 47(9): 1200-1204.

摘要 参考文献 相关文章 Metrics 全文: PDF(808 KB)   摘要: 参照含Nb锆合金中第二相的成分, 熔炼了(Zr, Nb)2Fe, Zr(Nb, Fe)2和β-Nb合金. 成分测试结果表明, 所炼合金的成分与锆合金中的第二相相同. XRD分析结果表明, 除(Zr, Nb)2Fe外, Zr(Nb, Fe)2和β-Nb合金的相结构也与锆合金中的第二相相同. 各合金的压力-成分-温度(P-C-T)曲线和吸放氢动力学曲线表明, 3种合金和纯Zr的可逆吸放氢能力按Zr(Nb, Fe)2, (Zr, Nb)2Fe, β-Nb和Zr顺序依次减弱. 关键词 ： P-C-T曲线,  吸放氢性能,  (Zr, Nb)2Fe,  Zr(Nb, Fe)2,  β-Nb     Abstract：Referring to the compositions of the second phases in zirconium alloys, (Zr, Nb)2Fe, Zr(Nb, Fe)2 and $\beta$--Nb were prepared. Chemical composition analysis results indicated that the compositions of the experimental alloys are the same as those of the second phases in zirconium alloys. XRD analysis indicated that the structures of Zr(Nb, Fe)2 and β-Nb alloys are the same as the second phases in zirconium alloys. The pressure-composition-temperature (P-C-T) curves and kinetic curves of hydrogen absorption and desorption were obtained. Experimental results showed that the reversible hydrogen absorption and desorption abilities (Hrev) decrease in the sequence of Zr(Nb, Fe)2, (Zr, Nb)2Fe, β-Nb and Zr. Key words： P-C-T curve    hydrogen absorption and desorption ability    (Zr, Nb)2Fe    Zr(Nb, Fe)2    β-Nb 收稿日期: 2011-03-02      基金资助: 国家高技术研究发展计划资助项目2008AA031701 作者简介: 王锦红, 女, 1985年生, 工程师 服务 把本文推荐给朋友 加入引用管理器 E-mail Alert RSS 作者相关文章 王锦红 王荣山 翁立奎 张晏玮 耿建桥 44.8K 链接本文: https://www.ams.org.cn/CN/10.3724/SP.J.1037.2011.00103      或      https://www.ams.org.cn/CN/Y2011/V47/I9/1200 [1] Charquet D, Hahn R, Ortlied E, Gros J P, Wadier J F. In: Van Swam L F P, Eucken C M eds., Zirconium in the Nuclear Industry: 8th International Symposium, ASTM STP 1023, Philadelphia: American Society for Testing and Materials, 1989: 405 [2] Kim H G, Park J Y, Jeong Y H. J Nucl Mater, 2005; 345: 1 [3] Jeong Y H, Kim H G, Kim T H. J Nucl Mater, 2003; 317: 1 [4] Toffolon–Masclet C, Barberis P, Brachet J C, Mardon J P, Legras L. J ASTM Int, 2005; 2(5): JAI12321 [5] Jeong Y H, Park S Y, Lee M H, Choi B K, Baek J H, Park J Y, Kim J H, Kim H G. J Nucl Sci Technol, 2006; 43: 977 [6] Rudling P, Wikmark G, Lehtinen B, Pettersson H, Andersson T, Pettersson H. In: Sabol G. P, Moan G. D eds., Zirconium in Nuclear Industry: 12th International Symposium, ASTM STP 1354, West Conshohocken: American Society for Testing and Materials, 2000: 678 [7] T¨agstrom P, Limb¨ack M, Dahlback M, Andersson T, Pettersson H. In: Moan G. D, Rudling P eds., Zirconium in Nuclear Industry: 13th International Symposium, ASTM STP 1423, West Conshohocken: American Society for Testing and Materials, 2002: 96 [8] HatanoY, Isobe K, Hitaka R, Sugisaki M. J Nucl Sci Technol, 1996; 33: 944 [9] Leli`evre G, Tessier C, Iltis X, Berthier B, Lefebvre F. J Alloys Compd, 1998; 268: 308 [10] Wang J H, Yao M Y, Zhou B X, Geng J Q, Zhang X, Zhang J L. Rare Met Mater Eng, 2011; 40: 1084 (王锦红, 姚美意, 周邦新, 耿建桥, 张欣, 张金龙. 稀有金属材料与工程, 2011; 40: 1084) [11] Hu Z L. Hydrogen Storage Materials. Beijing: Chemical Industry Press, 2002: 86 (胡子龙. 贮氢材料. 北京: 化学工业出版社, 2002: 86) [12] Yao M Y. PhD Thesis, Shanghai University, 2007 (姚美意. 上海大学博士学位论文, 2007) [13] Yao M Y, Zhou B X, Li Q, Liu W Q, Miao Z, Yu Y H. Rare Met Mater Eng, 2004; 33: 641 (姚美意, 周邦新, 李强, 刘文庆, 苗 志, 俞应华. 稀有金属材料与工程, 2004; 33: 641) [14] Yao M Y, Zhou B X, Li Q, Liu W Q, Wang S A, Huang X S. Rare Met Mater Eng, 2007; 36: 1915 (姚美意, 周邦新, 李 强, 刘文庆, 王树安, 黄新树. 稀有金属材料与工程, 2007; 36: 1915) [15] Liu Y P, Yao M Y, Zhou B X. J Shanghai Uni (Nat Sci), 2008; 4: 144 (鲁艳萍, 姚美意, 周邦新. 上海大学学报(自然科学版), 2008; 4: 144) [16] Yao M Y, Wang J H, Peng J C, Zhou B X, Li Q. J ASTM Int, 2011; 8(2): JAI102948 [17] Sabol G P, Kilp G R, Balfour M G, Roberts E. In: Van Swam L F P, Eucken C M eds., Zirconium in the Nuclear Industry: 8th International Symposium, ASTM STP 1023, Philadelphia: American Society for Testing and Materials, 1989; 227 [1] 马坪, 吴二冬, 李武会, 孙凯, 陈东风. Ti0.7Zr0.3(Cr1-xVx)2合金的结构和贮氢性能*[J]. 金属学报, 2014, 50(4): 454-462. [2] 李武会 田保红 马坪 吴尔冬. ScMn2合金贮氢(氘)性能[J]. 金属学报, 2012, 48(7): 822-829. [3] 李强 梁雪 彭剑超 刘仁多 余康 周邦新. Zr-2.5Nb合金中β-Nb相的氧化过程[J]. 金属学报, 2011, 47(7): 893-898. [4] 刘永锋; 潘洪革; 高明霞; 朱云峰; 葛红卫; 李寿权; 雷永泉 . 稀土镁基贮氢电极合金的结构与电化学性能研究[J]. 金属学报, 2003, 39(6): 666-672 . [5] 赵越; 郑华; 刘实; 杨锐; 王隆保 . Ti-Mo合金的结构及吸放氢性能研究[J]. 金属学报, 2003, 39(1): 89-93 . Viewed Full text Abstract Cited   Shared      Discussed