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金属学报  2017, Vol. 53 Issue (5): 615-621    DOI: 10.11900/0412.1961.2016.00332
  论文 本期目录 | 过刊浏览 |
Sn-Ag-Cu钎料焊接显微组织演化和性能研究
孙磊1,陈明和1(),张亮2,杨帆2
1 南京航空航天大学机电学院 南京 210016
2 江苏师范大学机电工程学院 徐州 221116
Microstructures Evolution and Properties of Sn-Ag-Cu Solder Joints
Lei SUN1,Minghe CHEN1(),Liang ZHANG2,Fan YANG2
1 College of Mechanical & Electrical Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, China
1 College of Mechanical & Electrical Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, China
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摘要: 

利用DSC、微焊点强度测试仪、SEM、EDS及XRD,研究了Sn0.3Ag0.7Cu、Sn1.0Ag0.5Cu和Sn3.0Ag0.5Cu钎料的熔化特性、润湿性、力学性能、显微组织及相种类。通过TL-1000型高低温循环试验箱测试了-55~125 ℃循环条件下Sn-Ag-Cu焊点的界面层变化。结果表明,随着Ag含量的增加,钎料的熔点变化不大,钎料的润湿角显著降低,N2氛围条件下,3种钎料的润湿性均出现明显的提高。此外,3种焊点的力学性能也随着Ag含量的增加显著提高。Sn0.3Ag0.7Cu、Sn1.0Ag0.5Cu焊点的基体组织存在着少量的Ag3Sn和大颗粒Cu6Sn5化合物,且分布杂乱,Sn3.0Ag0.5Cu焊点的基体组织则相对较为均匀,这也是Sn0.3Ag0.7Cu、Sn1.0Ag0.5Cu焊点的力学性能低于Sn3.0Ag0.5Cu的主要原因。对焊点进行热循环处理,发现3种焊点界面金属间化合物的厚度明显增加,界面层的形貌也由原来扇贝状向层状转化。

关键词 Sn-Ag-Cu润湿性力学性能显微组织热循环    
Abstract

SnAgCu solder alloys, such as Sn3.0Ag0.5Cu, Sn3.8Ag0.7Cu and Sn3.9Ag0.6Cu, are widely used for consumer electronics due to their good wettability, high mechanical properties and excellent thermal fatigue reliability. However, the high Ag content in SnAgCu solder can bring about a relatively high cost and poor drop impact reliability because of the formations of thicker brittle Ag3Sn compound during soldering. Therefore, the development of low Ag content SnAgCu solders to satisfy the requirements of electronic production has become a hot topic in this field. In this work, the effects of Sn0.3Ag0.7Cu, Sn1.0Ag0.5Cu and Sn3.0Ag0.5Cu solder on the melting character, wettability, mechanical properties and microstructures, phase composition were investigated by DSC, micro-joint strength tester, SEM, EDS and XRD. Under -55~125 ℃ cyclic conditions, the interfacial layer change of Sn-Ag-Cu solder joints was measured by TL-1000 high and low temperature test chamber. The results showed that, with the Ag content increased, the melting point was not changed, the wetting angle significantly decreased. And the wettability of three solders was improved under N2 atmosphere. Moreover, the mechanical properties of three solder joints were enhanced with the increase of Ag content. The matrix structure of Sn0.3Ag0.7Cu and Sn1.0Ag0.5Cu solder joint have a small amount of Ag3Sn and large Cu6Sn5 particles, and the distribution of particles were disordered. However, the matrix structure of Sn3.0Ag0.5Cu solder joint was obviously uniform. This is the reason that the mechanical properties of Sn0.3Ag0.7Cu and Sn1.0Ag0.5Cu solder joints were lower than that of Sn3.0Ag0.5Cu. In addition, the solder joints were subjected to a thermal cycling reliability test, it was found that the thickness of intermetallic compounds (IMCs) increased, and the morphology of IMCs was gradually changed from scallop-like to planar-like.

Key wordsSn-Ag-Cu    wettability    mechanical property    microstructure    thermal cycling
收稿日期: 2016-07-25      出版日期: 2017-02-23
基金资助:国家自然科学基金项目No.51475220,江苏省“六大人才高峰”高层次人才项目No.XCL022,江苏省“青蓝工程”中青年学术带头人计划,新型钎焊材料与技术国家重点实验室开放课题项目No.SKLABFMT201503,以及中国博士后科学基金项目No.2016M591464

引用本文:

孙磊,陈明和,张亮,杨帆. Sn-Ag-Cu钎料焊接显微组织演化和性能研究[J]. 金属学报, 2017, 53(5): 615-621.
Lei SUN,Minghe CHEN,Liang ZHANG,Fan YANG. Microstructures Evolution and Properties of Sn-Ag-Cu Solder Joints. Acta Metall, 2017, 53(5): 615-621.

链接本文:

http://www.ams.org.cn/CN/10.11900/0412.1961.2016.00332      或      http://www.ams.org.cn/CN/Y2017/V53/I5/615

图1  无铅焊接回流曲线
图2  Sn-Ag-Cu焊点的力学性能测试示意图
图3  热循环实验的温度循环载荷曲线
Solder TS TL Melting
range
Under-
cooling
Sn0.3Ag0.7Cu 213.0 228.1 15.1 22.6
Sn1.0Ag0.5Cu 213.7 227.7 14.0 17.8
Sn3.0Ag0.5Cu 213.4 219.7 6.3 8.3
表1  Sn-Ag-Cu钎料的熔化温度
图4  不同氛围下Sn-Ag-Cu钎料的润湿角
图5  Sn-Ag-Cu钎料焊点的力学性能
图6  Sn-Ag-Cu焊点断口SEM像
图7  Sn3.0Ag0.5Cu焊点的SEM像、EDS面扫描图及XRD谱
图8  Sn-Ag-Cu焊点基体组织的SEM像
图9  Sn-Ag-Cu焊点界面层的SEM像
图10  热循环500 cyc后Sn-Ag-Cu焊点界面层的SEM像
图11  不同热循环时间下Sn-Ag-Cu 焊点的界面层厚度
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