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金属学报  2016, Vol. 52 Issue (5): 625-631    DOI: 10.11900/0412.1961.2016.00013
  论文 本期目录 | 过刊浏览 |
梯度NiCoCrAlYSi涂层的循环氧化及热腐蚀行为*
彭新1,2,姜肃猛3,孙旭东1(),宫骏3,孙超3
1 材料各向异性与织构教育部重点实验室, 东北大学材料科学与工程学院, 沈阳 110819
2 中航工业沈阳黎明航空发动机(集团)有限责任公司, 沈阳 110043
3 中国科学院金属研究所, 沈阳 110016
CYCLIC OXIDATION AND HOT CORROSION BEHAVIORS OF A GRADIENT NiCoCrAlYSi COATING
Xin PENG1,2,Sumeng JIANG3,Xudong SUN1(),Jun GONG3,Chao SUN3
1 Key Laboratory for Anisotropy and Texture of Materials (Ministry of Education), School of Materials Science and Engineering, Northeastern University, Shenyang 110819, China
2 AVIC Shenyang Liming Aero-engine (Group) Corporation Ltd., Shenyang 110043, China
3 Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
引用本文:

彭新, 姜肃猛, 孙旭东, 宫骏, 孙超. 梯度NiCoCrAlYSi涂层的循环氧化及热腐蚀行为*[J]. 金属学报, 2016, 52(5): 625-631.
Xin PENG, Sumeng JIANG, Xudong SUN, Jun GONG, Chao SUN. CYCLIC OXIDATION AND HOT CORROSION BEHAVIORS OF A GRADIENT NiCoCrAlYSi COATING[J]. Acta Metall Sin, 2016, 52(5): 625-631.

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摘要: 

采用电弧离子镀技术制备了普通NiCoCrAlYSi涂层和梯度NiCoCrAlYSi涂层, 分析了2种涂层的组织及结构, 对比研究了2种涂层分别在1000 ℃到室温的循环氧化行为和900 ℃的高温热腐蚀行为. 结果表明, 普通涂层由γ/γ′相、β相和α-Cr相组成, 梯度涂层外层富Al, 内层富Cr, Al和Cr在涂层中呈梯度分布. 循环氧化过程中梯度涂层外层充足的Al源维持表面Al2O3膜的形成和修复, 界面处富Cr(W, Re)相抑制涂层与基体的互扩散, 表现出良好的抗循环氧化性能. 热腐蚀过程中, NaCl的存在加速了腐蚀的进程, 2种涂层出现不同程度的内氧化和硫化, 普通涂层表面形成了非保护性的NiAl2O4尖晶石和NiO, 梯度涂层中外部富Al内部富Cr的梯度分布, 减缓了热腐蚀进程.

关键词 梯度涂层电弧离子镀循环氧化热腐蚀    
Abstract

MCrAlY (M=Ni and/or Co) coatings are widely used as overlays or bond coats for thermal barrier coatings due to their good performance against high temperature oxidation and hot corrosion. Usually, high Al content in the MCrAlY coatings can benefit the performance and lifetimes of the coatings. However, MCrAlY coatings usually contain only restricted Al content because high Al content might lead to brittleness and potential crack. Design of gradient coating can be used to solve the problem, since it can provide a balance between high Al content and high stress bearing ability. Therefore, much attention has been paid to coatings with gradient structures, and these coatings show good oxidation and corrosion resistance. In this work, a gradient and a conventional NiCoCrAlYSi coating were prepared by arc ion plating technique and subsequent annealing treatment. Cyclic oxidation tests of the two coatings were carried out between room temperature and 1000 ℃. The hot corrosion tests of the coatings were performed in two different mixed salts of 75%Na2SO4+25%K2SO4 and 75%Na2SO4+25%NaCl (mass fraction) at 900 ℃. The results indicated that the gradient coating possessed a graded distribution of Al-rich outer layer and Cr-rich inner layer after annealing treatment, and it showed better performance of re-healing alumina scale due to its possession of more β phase as Al reservoir during the cyclic oxidation. The degradation process of the gradient coating was favorably retarded by the formation of Cr(W, Re)-rich precipitates in the interdiffusion zone. In sulphates, the two coatings showed good corrosion resistance. The presence of NaCl aggravated the corrosion extent of the two coatings. Compared with the conventional coating, the gradient coating postponed the formation of internal oxidation and sulfidation, resulting from the gradient distribution of Al-enriched outer layer and Cr-enriched inner layer.

Key wordsgradient coating    arc ion plating    cyclic oxidation    hot corrosion
收稿日期: 2016-01-06     
ZTFLH:     
基金资助:*国家自然科学基金资助项目51001106
Material Co Cr Al Re Mo W Nb Si Y C B Ni
Ni-based alloy 9.0 4.5 6.0 3.9 1.8 8.5 1.6 - 0.002 Minor Minor Bal.
NiCoCrAlYSi target 2.0 16.0 19.0 - - - - 0.5 0.500 - - Bal.
表1  镍基合金基体及NiCoCrAlYSi靶材的成分
图1  退火态普通和梯度NiCoCrAlYSi涂层的XRD谱
图2  退火态普通和梯度NiCoCrAlYSi涂层的截面BSE像
图3  梯度NiCoCrAlYSi涂层退火后的截面元素分布图
图4  普通和梯度NiCoCrAlYSi涂层从1000 ℃到室温的的循环氧化动力学曲线
图5  普通和梯度NiCoCrAlYSi涂层从1000 ℃到室温循环氧化200 cyc后的XRD谱
图6  普通和梯度NiCoCrAlYSi涂层从1000 ℃到室温循环氧化200 cyc后的截面BSE像
图7  普通和梯度NiCoCrAlYSi涂层在900 ℃的腐蚀动力学曲线
图8  普通和梯度NiCoCrAlYSi涂层在900 ℃的75%Na2SO4+25%K2SO4盐中腐蚀100 h后的XRD谱
图9  普通和梯度NiCoCrAlYSi涂层在900 ℃的75%Na2SO4+25% K2SO4盐中腐蚀100 h后的截面BSE像
图10  普通和梯度NiCoCrAlYSi涂层在900 ℃的75%Na2SO4+25%NaCl盐中腐蚀100 h后的XRD谱
图11  普通和梯度NiCoCrAlYSi涂层在900 ℃的75%Na2SO4+25%NaCl盐中腐蚀100 h后的截面BSE像
[1] Li M H, Sun X F, Li J G, Zhang Z Y, Jin T, Guan H R, Hu Z Q.Oxid Met, 2003; 59: 591
[2] Nicholls J R, Stephenson D J.Met Mater, 1991; 7: 156
[3] Goward G W.Surf Coat Technol, 1998; 68: 73
[4] Meetham G W.Mater Sci Technol, 1986; 2: 290
[5] Salam S, Hou P Y, Zhang Y D, Wang H F, Zhang C, Yang Z G.Corros Sci, 2015; 95:143
[6] Srinivasan V, Cheruvu N S, Carr T J, Obrien C M.Mater Manuf Process, 1995; 10: 955
[7] Lee E Y, Chartier D M, Biederman R R, Sisson R D.Surf Coat Technol, 1987; 32: 19
[8] Tang F, Ajdelsztajn L, Schoenung J M.Oxid Met, 2004; 61: 219
[9] Padture N P, Gell M, Jordan E H.Science, 2002; 296: 280
[10] Nicholls J R, Simms N J, Chan W Y, Evans H E.Surf Coat Technol, 2002; 149: 236
[11] Guo M H, Wang Q M, Gong J, Sun C, Huang R F, Wen L S.Corros Sci, 2006; 48: 2750
[12] Jiang S M, Peng X, Bao Z B, Liu S C, Wang Q M, Gong J, Sun C.Corros Sci, 2008; 50: 3213
[13] Wang W X, Jiang S M, Wei G Z, Ma J, Gong J, Sun C.Acta Metall Sin, 2011; 47: 578
[13] (王维新, 姜肃猛, 卫广智, 马军, 宫骏, 孙超. 金属学报, 2011; 47: 578)
[14] Yu D Q, Lu X Y, Ma J, Jiang S M, Liu S C, Gong J, Sun C.Acta Metall Sin, 2012; 48: 759
[14] (于大千, 卢旭阳, 马军, 姜肃猛, 刘山川, 宫骏, 孙超. 金属学报, 2012; 48: 759)
[15] Xu C Z, Jiang S M, Ma J, Gong J, Sun C.Acta Metall Sin, 2009; 45: 964
[15] (徐朝政, 姜肃猛, 马军, 宫骏, 孙超. 金属学报, 2009; 45: 964)
[16] Xu C Z, Jiang S M, Bao Z B, Gong J, Sun C.Corros Sci, 2009; 51: 1467
[17] Gleeson B, Cheung W H, Dacosta W, Young D J.Oxid Met, 1992; 38: 407
[18] Felix P.Deposition and Corrosion in Gas Turbines. London: Applied Science Publish, 1972: 331
[19] Lindblad N R.Oxid Met, 1969; 1: 143
[20] Merchant S M, Notis M R.Mater Sci Eng, 1984; A66: 47
[21] Hancock P.Mater Sci Technol, 1987; 3: 536
[22] Eliaz N, Shemesh G, Latanision R M.Eng Fail Anal, 2002; 9: 31
[23] Rapp R A.Corros Sci, 2002; 44: 209
[24] McKee D W, Shore D A, Lurthra K L.J Electrochem Soc, 1978; 125: 411
[25] Gurrappa I.Oxid Met, 1999; 51: 353
[26] Tsaur C C, Roch J C, Chang Y Y.Mater Chem Phys, 2005; 91: 330
[27] Hossain M K, Saunders S R J.Oxid Met, 1978; 12: 1
[28] Deb D, Iyer S R, Radhakrishnan V M.Mater Lett, 1996; 29: 19
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