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金属学报  2015, Vol. 51 Issue (4): 385-392    DOI: 10.11900/0412.1961.2014.00434
  本期目录 | 过刊浏览 |
低碳钢烘烤硬化机制的内耗研究
李维娟(), 张恒毅, 付豪, 张建平, 戚翔宇
辽宁科技大学材料与冶金学院, 鞍山 114051
INTERNAL FRICTION STUDY OF MECHANISM OF BAKE-HARDENING ON LOW CARBON STEEL
LI Weijuan(), ZHANG Hengyi, FU Hao, ZHANG Jianping, QI Xiangyu
School of Materials and Metallurgy, University of Science and Technology Liaoning, Anshan 114051
引用本文:

李维娟, 张恒毅, 付豪, 张建平, 戚翔宇. 低碳钢烘烤硬化机制的内耗研究[J]. 金属学报, 2015, 51(4): 385-392.
Weijuan LI, Hengyi ZHANG, Hao FU, Jianping ZHANG, Xiangyu QI. INTERNAL FRICTION STUDY OF MECHANISM OF BAKE-HARDENING ON LOW CARBON STEEL[J]. Acta Metall Sin, 2015, 51(4): 385-392.

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摘要: 

测试了低碳钢不同退火温度下烘烤态的应力-应变曲线和烘烤硬化(BH)值以及变形态和烘烤态的内耗曲线, 研究了不同退火温度下的烘烤硬化机制. 结果表明, 退火温度由750 ℃逐渐提高到880 ℃, 应力-应变曲线均表现不连续屈服现象, 且屈服平台的锯齿状越来越明显, 屈服点延伸量不断增大. 退火温度由750 ℃提高到780 ℃, BH值降低, 变形态和烘烤态的Snoek峰高差值增大, SKK峰高降低, Kê峰变化不大, 固溶强化对烘烤硬化起主导作用. 退火温度由780 ℃逐渐提高到880 ℃, BH值不断增大, 变形态和烘烤态的Snoek峰高差值逐渐减小, SKK峰的驰豫强度逐渐增大, Kê峰变化不大, Cottrell气团强化对烘烤硬化的作用逐渐增强. 烘烤硬化机制是固溶强化、Cottrell气团强化和沉淀强化的共同作用.

关键词 烘烤硬化内耗固溶强化Cottrell气团强化沉淀强化    
Abstract

High strength steel plates are being applied more extensively in automobile industry under higher demands of weight reduction, safety and environmental protection. As one of the high strength steel plates for automobile body panel, bake-hardening steel plate is featured by low yield strength and good formability during stamping, and is particularly featured by improved yield strength through following paint baking process, exhibiting higher strength and anti-dent ability in service. Bake-hardening (BH) is closely related to interactions between interstitial atoms and crystal defects during baking process. In this work, BH mechanisms in low carbon steel are studied under different annealing temperatures by measuring and analyzing stress-strain curves and BH values in baked conditions, and internal friction curves in both deformed and baked conditions. The results show that when the annealing temperature increases gradually from 750 to 880 ℃, the stress-strain curves exhibit discontinuous yielding behavior with stronger serration of yield platform and continuous elongation of yield point. With the increase of the annealing temperature from 750 to 780 ℃, BH value decreases, difference between Snoek peak values in deformed and baked conditions increases, SKK peak value decreases, and Kê peak value does not change significantly, which indicates that solid solution strengthening dominates the BH. When the annealing temperature increases from 780 to 880 ℃, BH value continuously increases, difference between Snoek peak values in deformed and baked conditions gradually decreases, relaxation strength of SKK peak gradually increases, and Kê peak is stable, which indicates that Cottrell atmosphere strengthening is playing an increasing role in the BH. The BH is due to a combined mechanism contributed by solid solution strengthening Cottrell atmosphere strengthening and precipitation strengthening.

Key wordsbake-hardening    internal friction    solid solution strengthening    Cottrell atmosphere strengthening    precipitation strengthening
    
ZTFLH:  TG142.1  
基金资助:* 国家自然科学基金资助项目51274121
作者简介: null

李维娟, 女, 1966生, 教授

图1  低碳钢在不同退火温度下的显微组织
图2  低碳钢烘烤硬化(BH)态的应力-应变曲线
图3  低碳钢不同退火温度下的BH值
图4  低碳钢不同退火温度下的内耗曲线
图5  不同退火温度的变形态Snoek峰高(hs)和变形态与烘烤态Snoek峰高的差值(ht)
图6  不同退火温度下变形态与烘烤态的Kê峰
[1] De A K, Vandeputte S, De Coomana B C. Scr Mater, 1999; 41: 831
[2] De A K, Blauwe K D, Vandeputteb S, De Cooman B C. J Alloys Compd, 2000; 310: 405
[3] Zhao J Z, De A K, De Cooman B C. ISIJ Int, 2000; 40: 725
[4] Speer G J, Matlock K D. JOM, 2002; 54(7): 19
[5] Jiang H T, Kang Y L, Yu H. Auto Technol Mater, 2005; (3): 1
[5] (江海涛, 康永林, 于 浩. 汽车工艺与材料, 2005; (3): 1)
[6] Zhao J Z, De A K, De Cooman B C. Metall Mater Trans, 2001; 32A: 417
[7] Baird J D. Int Mater Rev, 1971; 16(1): 1
[8] Vasilyev A A, Leeb H C, Kuzmin L N. Mater Sci Eng, 2008; A485: 282
[9] Zhao J Z, De A K, De Cooman B C. Mater Lett, 2000; 44: 374
[10] De A K, Vandeputte S, De Cooman B C. Scr Mater, 2001; 44: 695
[11] Cottrell A H, Bilby B A. Phys Soc London, 1949; 62(1)A: 49
[12] Soenen B, De A K, Vandeputte S, De Cooman B C. Acta Mater, 2004; 52: 3483
[13] Wert C, Marx J. Acta Metall, 1953; 1: 113
[14] Wert C A. Phys Rev, 1950; 79: 601
[15] Wert C A. Physics, 1949; 20: 943
[16] Bagramov R, Mari D, Benoit W. Philos Mag, 2001; 81A: 2797
[17] Ji J W, Yu N. Prog Phys, 2006; 26: 296
[17] (戢景文, 于 宁. 物理学进展, 2006; 26: 296)
[18] Fang Q F, Wang X P, Wu X B, Lu H. Physics, 2011; 40: 786
[18] (方前锋, 王先平, 吴学邦, 鲁 卉. 物理, 2011; 40: 786)
[19] Ji J W, Liu F D, Wang D J, Che Y Y, Hua Q Z, Liu J M, Huang Z R. Acta Metall Sin, 1999; 35: 913
[19] (戢景文, 刘芬娣, 王登京, 车韵怡, 华桥柱, 刘建民, 黄镇如. 金属学报, 1999; 35: 913)
[20] Yu N, Liu Y G, Zhang Z B, Zhan H, Zhang J, Ji J W. J ShangHai JiaoTong Univ, 2010; 44: 624
[20] (于 宁, 刘永刚, 张志波, 詹 华, 张 建, 戢景文. 上海交通大学学报, 2010; 44: 624)
[21] Che Y Y, Sun Y J, Ji J W. J Northeastern Univ (Nat Sci), 1997; 18: 676
[21] (车韵怡, 孙玉杰, 戢景文. 东北大学学报(自然科学版), 1997; 18: 676)
[22] Che Y Y, Liu F D, Zeng G Y, Xu Y C, Ji J W. Acta Metall Sin, 1998; 34: 831
[22] (车韵怡, 刘芬娣, 曾桂仪, 许余昌, 戢景文. 金属学报, 1998; 34: 831)
[23] Yu N, Ji J W. Acta Metall Sin, 2002; 38: 230
[23] (于 宁, 戢景文. 金属学报, 2002; 38: 230)
[24] Ge T S. Solid Internal Friction Theoretical Basis. Beijing: Science Press, 2000: 62
[24] (葛庭燧. 固体内耗理论基础. 北京: 科学出版社, 2000: 62)
[25] De A K, Vandeputte S, De Cooman B C. J Mater Eng Perform, 2001; 10: 567
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